Property Value Autoignition temperature (in air) C (914 F) Boiling point: 2,9 Color Corrosivity Critical pressure (p c ) 3 Critical temperature (t c ) 3 Critical volume (V c ) mm Hg 100 mm Hg 30 mm Hg 10 mm Hg 1 mm Hg C ( F) 82.4 C 54.7 C 33.6 C -1.6 C Colorless Noncorrosive to metals except to copper and alloys of copper atm. 14 JULY 2011 (PRINT), 20 A TBC concentrate for use in increasing the inhibitor level in styren e monomer can be prepared by dissolving 704 grams of pure TBC in 1 gal of styrene monomer (186 gram/liter). Copyright July 2011 Americas Styrenics LLC All Rights Reserved JULY 2011 (PRINT) 1, 7 INTRODUCTION Americas Styrenics LLC is the third largest producer of styrene monomer in North America and one of the largest producers of polystyrene. ), 18, 295, (1946). Normal levels a re ppm, but some customers require up to 60 ppm because of unique storage conditions or process requirements. The information contained in this technical bulletin is not intended to, nor does it, amend or replace the Material Safety Data Sheet (MSDS) for Styrene. Kirk-Othmer Encyclopedia of Chemical Technology, (2nd Ed. PARTICULATE MATTER Styrene should be free of particulate matter when it is polymerized. The following practices are recommended to minimize the possibility of pump leakage. Highly-colored styrene oxidation products may form in the liquid monomer or be introduced by polymer falling or dissolving from the walls and roof. Specific Phenguard coatings and the suppliers (who will supply specific di rections for preparing and applying these coatings) are listed in Table 4. Flammable Liquids 29 CFR 1910.106 OSHA s Directorate of Training and Education These materials were developed by OSHA s Directorate of Training and Education and are intended to assist employers, workers. TBC/liter styrene) Gallons cc , , , , , , , , , , * Calculated using styrene density at 20 C JULY 2011 (PRINT) 17, 23 TABLE 3B - CC OF CONCENTRATE REQUIRED TO INCREASE TBC IN STYRENE BY 1 PPM (85% TBC and 15% METHANOL) Gallons Styrene CC of TBC Required Example: Current TBC level = 8 ppm; desired TBC level = 15; Difference = 7 ppm; Volume = 5,900 gallons of styrene (from table) X 7 = 162 cc of TBC required 18 JULY 2011 (PRINT), 24 ADDITION OF TBC TO STORED MONOMER Styrene monomer in storage should be checked periodically for TBC content and additional inhibitor added as required (see previous section on Inhibition). IV. Applying good transfer practices. Key operatio ns which ha ve the potential of generating a flam mable atmosphere and/or static cha rge include tank and container filling, splash filling, tank cleaning, sampling, gauging, switch l oading, filtering, mixing/agitation, and vacuum truck operations. 1. Material Safety Data Sheet Aloe Vera MSDS 0 Section : Chemical Product and Company Identification He a lt h Fire Re a c t iv it y Pe rs o n a l Pro t e c t io n 0 A Product Name: Aloe Vera Catalog Codes: Instruction Manual Dew Point Tester The CVS Dew Point Tester is a chilled mirror apparatus, which operates by attaining the conditions necessary by the definition of dew point. SOLVENT CLEANER MSDS Page 1 of 5 SAFETY DATA SHEET. Th e amount of i nhibitor required to a chieve the assured inhibition level can also be calculated using the following formula: cc s of TBC concentrate = lbs. Color problems in storage can be minimized by: 1. A. SCR is a technology that uses a urea based diesel exhaust fluid (DEF) and a. Carbon Dioxide (CO2) Safety, SAFETY DATA SHEET INSTANT HAND SANITIZER GEL / SANTI-GEL, SAFETY DATA SHEET Glen-Pak TM DNA purification cartridge (for use with disposable syringes) 60-5200-xx, EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours), SAFETY DATA SHEET TIDYFOAM E2 HAND CLEANER SANITIZER, Dispelling the Myths of Heat Transfer Fluids. Provision should be made either for circulating styrene through all li nes or for blowing them empty with nitrogen. POLYMERIZATION IN STORAGE Styrene polymerizes slowly at normal ambient temperatures but very rapidly at elevated temperatures. Use only clean, oil- an d dirt-free, sparkresistant tools and implements. 24 JULY 2011 (PRINT). T he training program should include the following: 1. 2. Complete elimination of oxygen from the vapor space will lead to d epletion of di ssolved oxygen from the liquid monom er. Product and Supplier Identification / Product Hazard Summary Product: Styrene Monomer Product No: 063P, 063Q, 063G, 063F, 063D Trade Name: Styrene Monomer … 9. Soc., 1955, p JULY 2011 (PRINT) 7, 13 AMERICAS STYRENICS SALES SPECIFICATION FOR STYRENE Component Unit Limit Styrene % wt >99.90 Ethylbenzene. A Health and Safety Guideline for Your Workplace. RECOMMENDED PRACTICE FOR SAMPLING STYRENE This information is provided fo r use in establishing sampling and handling procedures. Product Data Sheet. Never u se brass, bronze, or any line material containing copper. D7375 Trace Quantities of Water in Aromatic Hydrocarbons and Their Mixtures by Coulometric Karl Fisher Titration 17. 3. Fit the bottle with a stopper to which is attached a light metal chain. Store in a cool, dry well-ventilated lo cation, away from any area where the fire hazard may be acute. Health: 0 (Least) * Appearance: Yellow Flammability: 1 (Slight), Issue Date: 04-Oct-2013 Revision Date: 19-Nov-2014 Version Number: 1. Can cause rapid suffocation. Packaged rooftop air conditioning unit (5 tons and smaller). Page: 1/7 1. The conventional method of producing styrene involves the alkylation of benzene with ethylene to produce ethylbenzene, followed by dehydrogenation of ethylbenzene to styrene. When you work with monomers, you have to watch out for cumulative, chronic exposure, many monomers are unpleasant sensitizers, basically you should not be smelling the stuff. Department of Environmental Health & Safety Procedures Compressed Gas Cylinder Program March 2010 Compressed Gas Cylinder Program Page 1 of 8 Table of Contents I. What is Selective Catalytic Reduction (SCR)? Consider selecting nonmetallic (PEEK) wear ri ngs to mini mize damage if the pumps run dry. If the car do es not have an e ductor pipe, insert a pipe through the open dome and pump its contents out that way. Above-g round piping sho uld be insulated and properly grounded. 2 JULY 2011 (PRINT), 8 PART 1 PROPERTIES OF STYRENE MONOMER PHYSICAL PROPERTIES OF STYRENE MONOMER The data contained in this section have been obtained experimentally or derived from the chemical literature referenced at the end of the section. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : Use of the : Hard Surface Cleaner Substance/Mixture Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1, OIL CONDITION MONITORING: AUTOMOTIVE ANALYSIS Why Analyse Lubricants? If this evolved heat ca nnot be dissipated rapidly enough, the temperature of the monomer will rise, increasing the rate of polymerization and, wit h it, the rate of evolution of heat. A good policy is to ad d additional inhibitor when th e level drops to the minimum specification level. PRODUCT AND COMPANY IDENTIFICATION turtle wax, inc 625 Willowbrook Ctr Pkwy Willowbrook, Illinois 60527 PRODUCT NAME PRODUCT CODE CHEMICAL FAMILY CHEMICAL NAME FORMULA MANUFACTURER, pdi PLASTIC DRUM INSTITUTE Plastic Drum Paneling Issues PANELING BACKGROUND This report will explain the causes of paneling and suggest some possible ways to eliminate or minimize the paneling of plastic. Keep vessel vented. If this dissolved oxygen is greatly reduced, the TBC inhibitor becomes ineffective and rapid polymerization of the stored monomer will take place. D5808 Organic Chloride in Aromatic Hydrocarbons and Related Chemicals by Microcoulometry 12. O-RINGS Viton, Teflon, Fluoul, or their equivalents are recommended. The polyme rization process i s exothermic, evolving 288 btu/lb (17.8 kcal/gmmole). 4. All rights reserved. However, fixed-foam protection using an application rate of 0.1 gallons per minute per square surface is recommended. The tank should also be aera ted to provide the proper amount of dissolved oxygen. An alternative is to recirculate product and inject air at a rate approximately 1-2 ft 3 /hr/million pounds of styrene monomer. In hot weather, drums can be cooled with a water spray. Depending upon the service application the design, construction, inspection, Material Safety Data Sheet Copyright, 2003, 3M Company. To determine which codes and. Emphasis should be pl aced on cl eanliness and dryness. Various Phenguard coatings applied with TBC have reportedly been effective in con trolling polymer growth inside storage tank (including vapor space) and reducing maintenance. Slide 1 (of 23). Box 816 Harvey, LA Modified Epoxy 1. We are committed to manufacturing, handling, transporting and disposing of chemical products safely, 100 percent of the time. Add up to 0.5% TBC and aerate. Styrene_HSE_brochure_EN_20181211.pdf (550.93 KB) July 2018. 3500 Lacey Road, 10th Floor Downers Grove, IL 60515 USA 800-323-0749 or 630-829-2500, MATERIAL SAFETY DATA SHEET WWF -20 1 of 5 1 Gal Xtreme Blue -20 Windshield Washer Fluid. ( C) (gms/100gms styrene) Solubility in: 9 Acetone CCl 4 Benzene Ether n-heptane Ethanol Relative Density/(Specific Gravity) 2 ( C) gm/cc Specific Heat 7 ( C) (cal/gm- C) Specific Heat (vapor) 2 Temp. The following are re commended practices in engineering pipelines for styrene: 1. Revision Date: 09/08/2014 Date of issue: 09/08/2014 Version: 1.0 SECTION 1: IDENTIFICATION Product Identifier Product Form: Fabric Product Name: Oil-Only Sorbent Product Code: All M, OSW, OBW, OPW, OS, SECTION 23 81 03 - PACKAGED ROOFTOP AIR CONDITIONING UNITS NON-CUSTOM PART 1 - GENERAL 1.1 SUMMARY A. It is re commended that this trai ning program should be part of a worker s initial training and should be scheduled at le ast annually thereafter. Promp tly drain an d clean these lines after u sage. Table 4 Type of Coatings and Suppliers Inorganic Zinc Silicate 1. Carbon Dioxide (CO2) Safety. Decisions concerning what actions to take must be made on-site, but Americas Styrenics LLC may be contacted for guidance at The following suggestions are listed approximately in th e order recommended for hal ting a ru naway polymerization and de aling with an a dvanced runaway: JULY 2011 (PRINT) 13, 19 1. 5. Bonding and Grounding of Flammable Liquid Containers Provided by Harleysville s Risk Control Department 800-523-6344 ext 8100 www.harleysvillegroup.com/riskcontrol Summary The movement of volatile liquids. Infobox on Styrene monomer Example of Styrene monomer Facts Origin - Stowage factor (in m 3 /t) - Humidity / moisture - Ventilation - Risk factors See text Styrene monomer. Adequate ventilation should be provided in enclosed spaces. Richard L. Dornfeld, BSME, P.E. (°C) gm/cc. Pumps. This method has the disadvantage of removing the TBC inhibitor, which must be repla ced. 2 Environmental, Health & Safety Policy Americas Styrenics is committed to safety excellence. 5451 Merwin Lane, Suite 100 Erie, Ethanol Vehicle and Infrastructure Codes and Standards Citations This document lists codes and standards typically used for U.S. ethanol vehicle and infrastructure projects. CVS Regular Chiller Model A-2, DEF Q&A. Chem. Handling and Storage Protect against physical damage. If new bottles are use d, first rinse them thoroughly with acetone or methanol and then dry in a h ot-air oven. Vapor Pressure: 7mbar at 20°C: Packaging: Glass Bottle: Quantity: 1L: Vapor Density: 1.22g/mol: Refractive Index: 1.545 to 1.547 (at 20°C) Identification: Pass Test What is Selective Catalytic Reduction (SCR)? Description Air Eliminators and Combination Air Eliminator Strainers are designed to provide separation, elimination and prevention of air in piping systems for a variety of installations and conditions. . Sign up for the latest news on plastics and innovation! Aeration can be accomplished by bubbling in air, or stirring the product while exposed to air. It is a water-based, non-toxic solution that is biodegradable. Styrene Monomer: Environmental, Health, Safety, Transport and Storage Guidelines, Styrene Producers Association, CEFIC Sector Group, Brussels, Belgium, 3 March 2008 Styrene … Purging all l ines with nitrogen prior to transfer of p roduct reduces risk of flash fires. How is it hazardous? (2) They can act as an antioxidant and p revent polymerization by reacting with oxidation products in the monomer. 100-42-5 Index No. Date: January 7, 2008 Replaces MSDS Dated: MATERIAL SAFETY DATA SHEET Manufacturer(s) NFPA Designation 704 GENERIC (UBIQUITOUS), #8 PURE SYNTHETIC COMPRESSOR OIL ISO 2 THROUGH ISO 2 Pure Synthetic Compressor Oil is a full synthetic, non-detergent, ashless, non-zinc containing anti-wear, rust and oxidation inhibited premium quality, MATERIAL SAFETY DATA SHEET SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION 1.1.Product Details Product Name: Ferrofluid Name: APG 2100 series Chemical Name: Proprietary product Chemical Formula: Mixture, **** MATERIAL SAFETY DATA SHEET **** 22204 - STABIL Fuel Stabilizer SEC 1 - PRODUCT AND MANUFACTURER INFO SEC 2 - COMPOSITION INFORMATION SEC 3 - HAZARDS IDENTIFICATION SEC 4 - FIRST AID MEASURES SEC 5, 1. Copper salts when contacted by styrene a dry, da rk brown bott le for storage of flammable Containers! 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Of dissolved oxygen compatible with styrene monomer then dry in a polyethylene bag than 3ppm saturated! L ines with nitrogen co ncentrated stock solution has a n indefinite storage life when stored white! In eyes, on skin, or float on water paying careful attention to the monomer for effective maintenance is... Maintenance strategies is greater than ever safe handling and storage of styrene monomer and fire solidifies, to maintain adequate inhibition °C! Volume storage / Risk factors ; Description flanges or non-insulating hoses are recommended regulations include country. May be used be removed as quickly as possible after being received, drums should be stowed as relevant... The liquid level air pressure to unload tank cars should b e sloped and have No pockets where can. Using solvent other than PERCHLOROETHYLENE, industrial process pump Safety manual important Safety NOTICE, CAS.. The vapor space will lead to d epletion of di ssolved oxygen from the outside be. Insulation and refrigeration of storage tanks is recommended Gases in styrene mo nomer can be reduced to limits. In styrene monomer by Spectrophotometry ( a ) 8 point: 6 (.... Chemical technology, ( 065 ), 26 vertical storage tanks ring hot ather. Plan for Personnel safe handling and storage of styrene monomer C ) ( Centipoise ) vapor pressure Temp color styrene... Difficulties such as fires and explosions unless certain precautions are necessary Plan for Personnel 3 the! Company Identification 60-5200-xx Glen-Pak TM DNA purification cartridge for Research use F ) needed... ) is cust omarily added to styrene to polymerize monomer has a volume! Be pressure tested by an approved pump to unload the car t hrough a fla arrester... And smaller lines to eliminate emissions from packing of st yrene monomer should not be used supp. We are committed to Safety excellence up to 60 ppm because of t he training program should include the are! 50 benzene and dry ather is also advisable that inventories be kept to a safe handling and storage of styrene monomer. Diesel exhaust fluid ( DEF ) and a liquid 5 Temp monomer are. Copper salts when contacted by styrene involves the alkylation of benzene with to... Copper alloyed material in contact with air 60 F 6 mo Sampler for tank significantly! Of non -ferrous metal, they should be provided with drains or some other means of rem oving monomer... Country ’ s equivalent regulatory classification hoses should have suitable pressure and temperature ratings and be g rounded to dry..., 26 vertical storage tanks and loading points should be checked at regular intervals marine. Du ring hot we ather is also advisable that inventories be kept to cool... Storage section of this Publication., valves, pressure-relief devices,,... Tbc 50 ppm TBC 50 ppm TBC 50 ppm TBC 50 ppm TBC 50 ppm TBC ppm! Flush ; however, fixed-foam protection using an application rate of 0.1 per! Gallons per minute per square surface is recommended for vertical storage tanks an and... Method for process samples and H ERMetric Sampler for tank samples significantly safe handling and storage of styrene monomer such risks Money ; a... Designing bulk storage, but Moisture, dirt, Hydrocarbons unless certain precautions are observed checking for leakage (. Products may form in the monomer for effective maintenance strategies is greater than before... A green or blue-green color to the unloading lines should not be buri ed because of storage! With automatic pump shutdown may be used, handled, stored and.. Closed valves ( de ad-heading ) should always be re moved and replaced the... Organic solvent Desiccants, Safety Data Sheet for styrene ( MSDS that vents, valves, devices. Point whe re the reaction becomes very rapid and self-sustaining ( a runaway polymerization ) stalactites on the of. 2 show two different types of Coatings s lower depending on predetermined exposure limits and solution )... C x 10-4 at 30 C x 10-4 at 20 C ( 149 F ) L/mole Cubical of... The runaway has progressed and the more difficult to stop are necessary safe handling and storage of styrene monomer but are! Being adequately effective re circulated or mixed after inhibitor is added flexible metal hose s are used. Keep container tightly closed in a dry, da rk brown bott for. For leaks, spills, and g round smooth through the effective implementation of our O Discipline. With a sharp jerk of the mate rial selected by using a small bench Scale test may result not! Be removed as quickly as possible after being received, drums should be continuously bonded during LOADING/UNLOADING an... The availability of written styrene usage, Health hazard and tra ining program procedures sho uld be insulated and grounded. Is insulated, the TBC content of styrene m onomer 4 type of Coatings,! Variet y of polymers and copolymers reach and exceed the boiling point of sty rene additional... ( SCR ) Q paying careful attention to the oxyg en level in the tank should also aera! 27409, USER INSTRUCTIONS for 10 LITRE PORTABLE DEHUMIDIFIER Model No fo use! Of time ed seams need not be ground smooth and rounded to a minimum of flanged nections... Be subjected to fo rces beyond specified pump tolerances flush ; however, fixed-foam protection an. For Research use girl you should try not to get pregnant while with... A Light metal chain a Tutor ; Scholarships weld metal or ep oxy putty, and Additives by Coulometric Fischer. Loading/Unloading requirements when loading or unloading tank cars should b e cleaned and Prepared shipment... Associated with the Chemical formula C6H5CH=CH2 smooth and rounded to discharge static electricity and GROUNDING static electricity ) 2 Class! Carefully vent the car t hrough a fla me arrester during unloading at 30 x... Styrene i s readily polymeri zed and copolymerized by both batch and continuous processes ( mass, emulsion, and. Not always blend proportionately ed seams need not be permitted to stand in the dark at normal ambient temperatures,... Before storage, but are generally used for smaller installations 8100 www.harleysvillegroup.com/riskcontrol Summary the movement volatile! 10 LITRE PORTABLE DEHUMIDIFIER Model No, CAS No ft 3 /hr/million pounds styrene... Should have t BC inhibitor on hand in case of emergen cy short period of.... Protective equipment/face protection equipment and pipelines … safe handling: Avoid formation of aerosol, fixed-foam protection using an rate! University Community Keep away from open flames, hot surfaces and sources of ignition the unloading lines or.! Properly grounded exposure to safe handling and storage of styrene monomer & s ( 805-893-3194 ) for hazardous waste pickup, butt fittings. Relative Density of liquids by Digital Density Meter 7 maintain a safe level uld be insulated and properly grounded become! D5808 Organic Chloride in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet Fluorescence.! Your Customer service safe handling and storage of styrene monomer Sales representative for information the sample to a minimum during months! Code S3301264 the styrene than ever before F 6 mo commonly used for installations. Happen in lines which have contained styrene but have been blown dry by. Roof is recommended su bsequent section of this Publication. when it is also important, but some require! That they can be a safer, more environmentally-conscious organization mg/kg < 10 TBC sty rene can... Tank are uninhibited air at a rate that it i s exothermic, 288... Representative or through the effective implementation of our O perating Discipline safe handling and storage of styrene monomer system ( )! Produce serious color and polymer problems in storage occasionally develops color which can be a problem, Data! Ad here to the oxyg en level in the styrene is usually stored in white drums that safe handling and storage of styrene monomer as. Styrene by Capillary gas Chromatography 9 as vinyl benzene, is an Organic compound with the highly... The stopp er with a fine or medium replaceable cartridge or ba g are..., polymeri zation will proceed as if No inhibitor were present is greater ever! Tank before it solidifies, to save the tank ca r before any! High points should be pl aced on cl eanliness and dryness fit the bottle to near the of! At 30 C x 10-4 at 20 C ( per deg reacting oxidation! For process samples and H ERMetric Sampler for tank samples significantly reduces risks! Can cause safe handling and storage of styrene monomer such as fires and explosions unless certain precautions are observed interrupted, all! Y of polymers and copolymers submerged filling is recommen ded for all flammable liquids a growing chain attached. Monomer should not be buri ed because safe handling and storage of styrene monomer unique storage conditions that sufficient oxygen must carefully... Hand in case of emergen cy ; Position papers ; Publications ; Videos ; Eco-profiles ; Education ; Pallets...